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Research Interests
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- Synthesis and development of oxide materials for nanotechnology
- Agglomeration strength of nano-powders
- Point defect chemistry
- Electroceramics and electroceramic devices
- Impedance measurements and analysis
- Detection and analysis of out-of-range phenomena and ill-posed inverse problems
- Sustainable Energy
Some Examples of our research are explained
Below:
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Defect chemistry of perovskites
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Here we were involved in understanding the role of metal vacancies in barium
titanate and revisiting accordingly the subject of defect chemistry of barium
titanate and similar materials. We were also involved in finding the trends of
site occupancy of trivalent dopants in barium titanate, and explaining the role
of some of these dopants in life-time improvement of capacitors. We have
demonstrated the importance of oxygen activity in the very early sintering of
nanopowders.
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Impedance spectroscopy measurements and other ill-posed inverse problems
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One of our main tools for analyzing electrical properties is impedance spectroscopy.
The analysis of impedance spectroscopy data is an ill-posed inverse problem. We
have developed not only experimental setup but also a new approach for dealing
with the data, taking advantage of the pre-knowledge about the system. We are
currently applying genetic algorithms to improve the analysis of such problems.
We have applied our new approach to analysis of other inverse problems, notably
scatterometry of deep UV light for line edge roughness detection. This was done
in cooperation with Nova Ltd. Our new approach makes it possible to put a
relatively cheap machine in-line and detect all the wafers at a rate of seconds
per wafer.
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Synthesis of nano-ceramic materials
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We learn and develop synthesis routes to obtain and stabilize nanopowders, in
particular of ceramic materials. This includes hydrothermal synthesis of barium
titanate (pure and doped); hydrolysis of titania and titania-niobia solid
solutions; hydrolysis of zinc peroxide nanoparticles and production of zinc
oxide nanoparticles; combustion synthesis of perovskites and of silver embedded
in carbon nanoparticles. It is important to produce the nanopowders that we
investigate in our lab, since nanopowders are typically systems that are not in
thermodynamic equilibrium, and hence their properties are strongly influenced by
the synthesis route, on which we would like to have control. Great deal of our
efforts in this area is directed to the development of simple, inexpensive and
preferably water based routes. We now use nanopowder of barium titanate that we
synthesize and stabilize in our lab to create thin films of sintered barium
titanate on Ni electrodes by cathodic water-based electrophoretic deposition.
This may open a new way to prepare complex shapes of dielectric material on a
cheap electrode via environmentally benign route
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Agglomeration strength of nanomaterials
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One of the most important practical problems when dealing with nanopowders is
its tendency to agglomerate. We are developing a new method to measure directly
the agglomerate strength of nanomaterials. Individual agglomerates are fixed
onto a hard substrate and their strength is measured by nanoindentation. We
proposed that the agglomerate strength can be correlated with the shape of the
nanoindentation load-displacement curves. This was already demonstrated on
silver, barium titanate, ceria, titania and other nanopowders.
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Technion Energy Program
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Prof. Tsur serves as a member in the Technion’s committee that is responsible to establish a coherent effort within
the Technion in energy research and education. He is the coordinator of the fuel cells program,
and a member in the graduate program committee.
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