Publications

2024

Studying the Effect if Operating Conditions and NO2 Cathode Contamination on PEM Fuel Cells Using Distribution Function of Relaxation Times Analysis

W. Khalaily, S. Bhowmick and Y. Tsur

ChemSusChem (2024), DOI: 10.1002/cssc.202401488

The Influence of Point Defects on the Sintering of Magnesium Oxide

R. Halabi, S. Simotko, Y. Tsur

Journal of the American Ceramic Society,1–13 (2024), DOI: 10.1111/jace.20090

Advancing Electrochemical Impedance Analysis Through Innovations in the Distribution of Relaxation Times Method

A. Maradesa, B. Py, J. Huang, Y. Lu, P. Iurilli, A. Mrozinski, H.M. Law, Y. Wang, Z. Wang, J. Li, S. Xu, Q. Meyer, J. Liu, C. Brivio, A. Gavrilyuk, K. Kobayashi, A. Bertei, N.J. Williams, C. Zhao, M. Danzer, M. Zic, P. Wu, V. Yrjänä, S. Pereverzyev, Y. Chen, A. Weber, S.V. Kalinin, J.P. Schmidt, Y. Tsur, B.A. Boukamp, Q. Zhang, M. Gaberšček, R. O’Hayre and F. Ciucci

Joule (2024), DOI: doi.org/10.1016/j.joule.2024.05.008

2023

Distribution Function of Relaxation Times: An Alternative to Classical Methods for Evaluating the Reaction Kinetics of Oxygen Evolution Reaction

R. Attias, S. Bhowmick and Y. Tsur

Chemical Engineering Journal, 476, 146708 (2023)

Quantifying the Resistive Losses of the Catalytic Layers in Anion-Exchange Membrane Fuel Cells

J. C. Douglin, K. V. Sankar, AL. G. Biancolli, E. I. Santiago, Y. Tsur and D. R. Dekel

ChemSusChem, (2023), doi.org/10.1002/cssc.202301080

2022

Investigation of Thermo-Chemical Expansions in Pr and Gd Doped Ceria by a Novel Temperature Modulated Dilatometry Approach

A. K. Baral and Y. Tsur

Journal of the European Ceramic Society, 42, 2299-2306 (2022)

2021

Uncovering the Change in Catalytic Activity during Electro-oxidation of Urea: Answering Overisolation of the Relaxation Phenomenon

B. Malik, K. Vijaya Sankar, SKT. Aziz, S Majumder, Y. Tsur and G.D Nessim

Journal of Physical Chemistry C, 125, 42, 23126-23132 (2021)

Influence of Isovalent ‘W’ Substitutions on the Structure and Electrical Properties of La2Mo2O9 Electrolyte for Intermediate-Temperature Solid Oxide Fuel Cells

T. Paul Y. Tsur

Ceramics,  4, 502–515 (2021)

Flash‐Sintering Mechanism Studied Through Interrupted Experiments

M. Z. Becker, S. Baltianski, L. Popilevsky, R. Attias, T. Paul and Yoed Tsur

Advanced Engineering Materials, 23 (7), 2001499 (2021) 

Development of a Typical Distribution Function of Relaxation Times Model for Polymer Electrolyte Membrane Fuel Cells and Quantifying the Resistance to Proton Conduction within the Catalyst Layer

G. Avioz Cohen, D. Gelman and Y. Tsur

Journal of Physical Chemistry C, 125 (22), 11867-11874 (2021) 

Optimization of Ni−Co−Fe‐Based Catalysts for Oxygen Evolution Reaction by Surface and Relaxation Phenomena Analysis

R. Attias, K. V. Sankar, K. Dhaka, W. Moschkowitsch, L. Elbaz, M. Caspary Toroker and Y.Tsur 

ChemSusChem, 14, 1737–1746 (2021)

Determining the Electrochemical Oxygen Evolution Reaction Kinetics of Fe3S4@Ni3S2 Using Distribution Function of Relaxation Times

B. Malik, K. V. Sankar, R. Konar, Y. Tsur and G. D. Nessim

ChemElectroChem, 8 (3), 517-523 (2021)      

Bifunctional PGM-Free Metal Organic Frameworks-based Electrocatalysts for Alkaline Electrolyzers: Trends in the Activity with Different Metal Centers

W. Moschkowitsch, S. Gonen, K. Dhaka, N. Zion , Y. Tsur , M. Caspary Toroker and L. Elbaz   

Nanoscale, 13 (8), 4576-4584 (2021)    

2020

Interphases Formation and Analysis at the Lithium–Aluminum–Titanium–Phosphate (LATP) and Lithium–Manganese Oxide Spinel (LMO) Interface during High-Temperature Bonding

O. Levit, P. Xu, B. Shvartsev, G. Avioz Cohen, L. Stanciu, Y. Tsur and Y. Ein-Eli

Journal of Energy Technology, 2000634, 1-12 (2020)

Tri‐Functional Double Perovskite Oxide Catalysts for Fuel Cells and Electrolyzers

A. K. Baral, K. V. Sankar, A. Matatyaho, G. Kushnir and Y. Tsur 

ChemSusChem, 13, 1-13 (2020)   

Fabrication of nickel-yttria stabilized zirconia 3D micro-pattern by atmospheric plasma spray as a dual-functional electrocatalyst for overall water splitting applications in alkaline medium

S. Sivakumar , S. Yugeswaran,  K. V. Sankar, L. Kumaresan, G. Shanmugavelayutham, Y. Tsur and J. Zhu

Journal of Power Sources, 473, 228526 (2020)                                                   

Studies on Effect of Ca-Doping on Structure and Electrochemical Properties of Garnet-type Y3-xCaxFe5O12-δ

Z. Zhang, K. Singh, Y. Tsur, J. Zhou, J. J. Dynes and V. Thangadurai

Journal of Solid State Chemistry, 290, 121530 (2020)   

Ternary NiFeTiOOH Catalyst for the Oxygen Evolution Reaction: Study of the Effect of the Addition of Ti at Different Loadings

W. Moschkowitsch, K. Dhaka, S. Gonen, R. Attias, Y. Tsur, M. Caspary Toroker and L. Elbaz 

ACS Catalysis, 10, 9, 4879–4887 (2020)                                                   

Electrochemical Activation of Li2MnO3 Electrodes at 0 °C and Its Impact on the Subsequent Performance at Higher Temperatures

F. A. Susai, M. Talianker, J. Liu, Rosy, T. Paul, Y. Grinblat, E. Erickson, M. Noked, L. Burstein, A. I. Frenkel, Y. Tsur, B. Markovsky and D. Aurbach

Materials, 13(19), 4388 (2020)   

Electrochemical Impedance Spectra of RuO2 During Oxygen Evolution Reaction Studied by the Distribution Function of Relaxation Times

K. V. Sankar, R. Attias and Y. Tsur

Electrochemistry Communications, 110, 106641 (2020)                                 

Preformed Oxide Scale Chemistry and Its Influence on Local Metal Loss During Dual Atmosphere Corrosion

M. Reisert, A. Aphale, Y. Tsur and P. Singh 

The Minerals, Metals & Materials Society (eds) TMS 2020 149th Annual Meeting & Exhibition Supplemental Proceedings, 635-645 (2020)    

2019

Femtosecond Laser Processing of Ceria-based Micro Actuators

E. Mishuk, J. Shklovsky, Y. Berg, N. Vengerovsky, T. Paul, Z. Kotler, Y. Tsur, Y. Shacham-Diamand, S. Krylov and I. Lubomirsky

Microelectronic Engineering, 217, 111126 (2019)                                        

Electro‐chemomechanical Contribution to Mechanical Actuation in Gd‐Doped Ceria Membranes

E. Mishuk, A. Ushakov, E. Makagon, S. R. Cohen, E. Wachtel, T. Paul, Y. Tsur, V. Y. Shur, A. Kholkin and I. Lubomirsky

Advanced Materials Interfaces, 6 (6), 1801592 (2019)   

Determination of Grain Boundary Conductivity using Distribution Function of Relaxation Times (DFRT) Analysis at Room Temperature in 10 mol% Gd Doped Ceria: A Non-Classical Electrostrictor

T. Paul, N. Yavo, I. Lubomirsky, and Y. Tsur 

Solid State Ionics, 331, 18-21 (2019)  

Sintering Aid (ZnO) Effect on Proton Transport in BaCe0.35Zr0.5Y0.15O3‐δ and Electrode Phenomena Studied by Distribution Function of Relaxation Time

A. K. Baral and Y. Tsur 

Journal of American Ceramic Society, 102, 239–250, (2019)                 

Electrochemical Studies of Ruddlesden-Popper Layered Perovskite-type La0.6Sr1.4Co0.2Fe0.8O4+δ Cathode for Solid Oxide Fuel Cells and Associated Electrical Loss Phenomena

A. K. Baral, Y. Tsur, and V. Thangadurai

Ceramics International, 45, 1641-1650 (2019)   

2018

Understanding of Oxygen Reduction Reaction on Perovskite-Type Ba0.5Sr0.5Fe0.91Al0.09O3-δ and Ba0.5Sr0.5Fe0.8Cu0.2O3-δ Using AC Impedance Spectroscopy Genetic Programming

A. Oz, K. Singh, D. Gelman, V. Thangadurai, and Y. Tsur

Journal of Physical Chemistry C, 122, 15097–15107 (2018)                 

Effect of Isovalent Doping on Grain Boundary Conductivity for La2Mo2O9 Oxide Ion Conductor: A Distribution Function of Relaxation Times Approach

T. Paul and Y. Tsur

Solid State Ionics, 323, 37-43, (2018)      

Understanding Methods of Preparation and Characterization of Pore-Filling Polymer Composites for Proton Exchange Membranes: A Beginner’s Guide

R. Gloukhovski, V. Freger and Y. Tsur

Reviews in Chemical Engineering, 34 (4), 455-479, (2018)   

Recent Advances in Mechanism Research and Methods for Electric Field Assisted Sintering of Ceramics

M. Z. Becker; N. Shomrat and Y. Tsur 

Advanced Materials, 1706369, (2018)     

Data for New Protocol to Detect the Monoclinic Phase of La2Mo2O9 and Related Oxide Ion Conductors

T. Paul and Y. Tsur                                                                                              

Data in Brief, 18, 1637-1641, (2018)  

A Protocol to Detect the Phase Transition in La2Mo2O9 Oxide Ion Conductor

T. Paul and Y. Tsur 

Materials Letters, 220, 325-327, (2018)  

2017

An Aluminum – Ionic Liquid Interface Sustaining a Durable Al-Air Battery

D. Gelman, B. Shvartsev, I. Wallwater, S. Kozokaro, V. Fidelsky, A. Sagy, A. Oz, S. Baltianski, Y. Tsur and Y. Ein-Eli   

Journal of Power Sources, 364, 110-120, (2017)  

A Novel Approach for Supercapacitors Degradation Characterization

A. Oz, D. Gelman, E. Goren, N. Shomrat, S. Baltianski, and Y. Tsur            

Journal of Power Sources, 335, 74-82, (2017)      

Impedance Spectroscopy of Gd-doped Ceria Analyzed by Genetic Programming (ISGP) Method

A. K. Baral and Y. Tsur 

Solid State Ionics, 304, 145-149, (2017) Doi:10.1016/j.ssi.2017.04.003  

Evolutionary Programming Based Approach for SOFC Cathode Characterization: A Case Study on Co-Free Mixed Conducting Perovskites

A. Oz, D. Gelman, Y. Tsur, K. Singh and V. Thangadurai 

ECS Trans, 78(1), 20992108, (2017)      

Novel Method for Determining the Width of the Electrochemically Active Electrode Area Along the Triple Phase Boundary

T. Beitner, S. Baltianski, R. Merkle, Y. Tsur, and I. Riess       

Solid State Ionics, 303, 70-77, (2017)

A Nafion-Filled Polycarbonate Track-Etched Composite Membrane with Enhanced Selectivity for Direct Methanol Fuel Cells

R. Gloukhovski, Y. Tsur, and V. Freger                             

Fuel Cells, 17, 56-66, (2017)

Vibrational and Impedance Spectroscopic Studies of Semi-Interpenetrating Polymer Networks Solid Polymer Electrolytes

N. Bar, P. Basak, and Y. Tsur        

Physical Chemistry Chemical Physics, 19, 14615–14624, (2017)

The Influence of Doping on Flash Sintering Conditions in SrTi1−xFexO3−δ

N. Shomrat, S. Baltianski, E. Dor, Y. Tsur        

Journal of the European Ceramic Society 37, 179–188, (2017)

2016

The Effects of Low Oxygen Activity Conditions on the Phase Equilibria and Cation Occupancy of Strontium Barium Niobate

J. A. Bock, J. H. Chan, Y. Tsur, S. Trolier-McKinstry, C. A. Randall     

Amer. Ceram. Soc., 99,3435-3442, (2016)

A Novel Composite Nafion/Anodized Aluminium Oxide Proton Exchange Membrane

R. Gloukhovski, V. Freger and Y. Tsur                    

Fuel Cells 16, 434–443, (2016)

Impedance Spectroscopy Analysis Inspired by Evolutionary Programming as a Diagnostic Tool for SOEC and SOFC

Z. Drach, S. Hershkovitz, D. Ferrero, P. Leone, A. Lanzini, M. Santarelli and Y. Tsur

Solid State Ionics, 288, 307-310, (2016) doi:10.1016/j.ssi.2016.01.001

Novel Method for Determining the Triple Phase Boundary width

T. Beitner, S. Baltianski, I. Riess and Y. Tsur

Solid State Ionics, 288, 322-324, (2016). doi:10.1016/j.ssi.2015.11.026

Analysis of Impedance Spectroscopy of Aqueous Supercapacitors by Evolutionary Programming: Finding DFRT from Complex Capacitance

A. Oz, S. Hershkovitz, N. Belman, E. Tal-Gutelmacher and Y. Tsur

Solid State Ionics, 288, 311-314, (2016). doi:10.1016/j.ssi.2015.11.008

2015

Flash Sintering of Potassium-Niobate

N. Shomrat, S. Baltianski, C.A. Randall and Y. Tsur

J. European Ceramics Society. 35 2209–2213, (2015)

The Use of 1, 10-Phenanthroline as an Additive for High-Performance Super Capacitors

A. Borenstein, S. Hershkovitz, A. Oz, Y. Tsur and D. Aurbach

J. Physical Chemistry C. 119 (22), 12165–12173, (2015)

2014

The Correlation between Non-Stoichiometry and Charge Compensation in Perovskites

N. Shomrat, D. Haviv and Y. Tsur

J. Electroceramics, 33, 135–141, (2014). (Feature article)

Electrochemical Impedance Spectroscopy of Supercapacitors: A Novel Analysis Approach using Evolutionary Programming

A. Oz, S. Hershkovitz and Y. Tsur

AIP Conference Proceedings 1627, 76-80, (2014)

Using Ellipsometry with Lock-in Detection to Measure Activation Energy of Ion Diffusion in Ionic and Mixed Conductors

G. Lazovski, E. Wachtel, Y. Tsur and I. Lubomirsky

Solid State Ionics, 264, 7-16 (2014) (Best paper award)

Resistive Switching Phenomena in TiOx Nanoparticle Layers for Memory Applications

E. Goren, M. Ungureanu, R. Zazpe, M. Rozenberg, L. E. Hueso, P. Stoliar, Y. Tsur, and F.Casanova

Applied Physics Letters, 105, 143506, (2014)

2013

Highly Porous Anode for Application in High-Temperature Electrochemical Devices

S. Tomer, S. Hershkovitz, S. Baltianski and Y. Tsur

Energy Technology, 1, 25-29, (2013)

2012

Electrochemical Impedance Analysis of SOFC Cathode Reaction using Evolutionary Programming

S. Hershkovitz, S. Baltianski and Y. Tsur

Fuel Cells, 12, 77-85, (2012)

2011

Utility of Resistance and Capacitance Response in Sensors based on Monolayer-Capped Metal Nanoparticles

G. Shuster, S. Baltianski, Y. Tsur, and H. Haick

J. Phys. Chem. Let., 2, 1912-1916, (2011)

ISGP: Impedance Spectroscopy Analysis Using Evolutionary Programming Procedure

S. Hershkovitz, S. Tomer, S. Baltianski and Y. Tsur

ECST, 40, 67-73, (2011)

Harnessing Evolutionary Programming for Impedance Spectroscopy Analysis: A Case Study of Mixed Ionic Electronic Conductors

S. Hershkovitz, S. Baltianski and Y. Tsur

Solid State Ionics, 188, 104-109, (2011)

Synthesis of Inside-Out Core-Shell Perovskite-type Oxide Nanopowder

O. Mazar, M. Schroeder and Y. Tsur

Chemical Engineering Journal, 166, 1139-1143, (2011)

2010

Highly Porous Anode for Application in Double Electrolyte Fuel Cell

S. Tomer, G. Grader and Y. Tsur

Fuel Cell, 1, 1192, (2010)

Analyzing Results of Impedance Spectroscopy using Novel Evolutionary Programming Techniques

A.B. Tesler, D.R. Lewin, S. Baltianski and Y. Tsur

Journal of Electroceramics, 24, 245-260, (2010)

2009

I-V Relations and Enhanced Mobility of Metal Vacancies in Acceptor Doped Poly Crystalline BaTiO3 under an Oxygen Activity Gradient

A. Ya’akobovich, S. Baltianski and Y. Tsur                 

Materials Science and Technology, 25, 1329-1333, (2009)

Eliminating Chemical Effects from Thermal Expansion Coefficient Measurements

M. Ram and Y. Tsur

Journal of Electroceramics, 22, 120-124 (2009)

Trials of a Novel Approach for the Analysis of Impedance Spectroscopy

S. Hershkovitz, S. Baltianski, Y.D. Horev, D.R. Lewin and Y. Tsur

Proc. of the Materials Science & Technology 2009 Conference & Exhibition, Pittsburgh, PA, 831-837, (2009)

2008

Recent Calculations and Measurements of I-V Relations in Simple Devices based on Thin Nano Versus Thick Layers of Semiconductors with Mobile Acceptors or Donors

Y. Gil, O.M. Umurhan, Y. Tsur and I. Riess

Solid State Ionics, 179, 1187–1193, (2008)

Properties of Solid State Devices with Significant Impurity Hopping Conduction

Y. Gil, Y. Tsur, O.M. Umurhan and I. Riess

Journal of Physics D: Applied Physics, 41, 135106-135116, (2008)

A Novel Method for Pushing the Limits of Line Edge Roughness Detection by Scatterometry

Y. Cohen, B. Yaakobovitz, Y. Tsur and D. Scheiner

Proceedings of SPIE, 6922, 692220, (2008)

I-V Relations in Nano Thin Semi-Conductors with Mobile Acceptors or Donors

Y. Gil, I. Riess, O.M. Umurhan and Y. Tsur

Solid State Ionics, 179, 24-32, (2008)

Synthesis of Stabilized Nanoparticles of Zinc Peroxide

L. Rosenthal-Toib, K. Zohar, M. Alagem, and Y. Tsur

Chemical Engineering Journal, 136, 425-429, (2008)

Nb-Doped Barium Titanate: Concentration-Properties Relations

S. Hershkovitz, S. Baltianski and Y. Tsur

Proc. of the 9th Biennial Conference on Engineering Systems Design and Analysis, ASME, 1, 499-504, (2008)

Preparation of Core-Shell Ti-Nb Oxide Nanocrystals

D.S.A. Simakov and Y. Tsur

Journal of Nanoparticle Research, 10, 77-85, (2008)

Preparation of Core-Shell Ti-Nb Oxide Nanocrystals

D.S.A. Simakov and Y. Tsur

Journal of Nanoparticle Research, 10, 77-85, (2008)

2007

Cathodic Electrophoretic Seposition of Barium Titanate Films from Aqueous Solution

H. Yaseen, S. Baltianski and Y. Tsur

Journal of Materials Science, 42, 9679–9683, (2007)

Surface Stabilization of Nano-sized Titanium Dioxide: Improving the Colloidal Stability and the Sintering Morphology

S.A. Simakov and Y. Tsur

Journal of Nanoparticle Research, 9, 403-417 (2007)

Line Edge Roughness Detection using Deep UV Light Scatterometry

B. Yaakobovitz, Y. Cohen and Y. Tsur

Journal of Microelectronic Engineering, 84, 619-625, (2007)

2006

Inter-Nanoparticle Bonds in Agglomerates Studied by Nanoindentation

Y. Raichman, M. Kazakevich, E. Rabkin and Y. Tsur

Advanced Materials, 18, 2028-2030, (2006)

Identification of the Early Stage of Sintering of Nano-BaTiO3: A Comparative Study

Y. Dror, R.D. Levi, S. Baltianski and Y. Tsur

Journal of the Electrochemical Society, 153, F137-F143, (2006)

Effect of Incorporating Method and Concentration of Niobium on the Properties of Barium Titanate Ceramics

H. Yaseen, S. Baltianski and Y. Tsur

Journal of the American Ceramic Society, 89, 1584-1589, (2006)

Analyzing Impedance Spectroscopy Results

Y. Tsur and S. Baltianski                                               

Rare Metal Materials and Engineering, 35, 452-454, Suppl. 3, (2006)  

2005

The Effect of Oxygen Vacancies in the Early Stages of BaTiO3 Nanopowder Sintering

R. D. Levi and Y. Tsur

Advanced Materials, 17, 1606-1608, (2005)

A Device for Measuring Electrical Properties of Dielectric Materials

Y. Melman, S. Baltianski and Y. Tsur

Instrumentation Science and Technology, 33, 279-287, (2005)

2004

Electron Paramagnetic Resonance Investigations of Lanthanide-Doped Barium Titanate: Dopant Site Occupancy

T.D. Dunbar, W.L. Warren, B.A. Tuttle, C.A. Randal, and Y. Tsur

J. Phys. Chem. B, 108, 908-917, (2004)

2003

Solubility of Pr in Barium Titanate

E. Aizinger, R. Ben David, H. Yaseen and Y. Tsur

The IIChE e-Journal, 1, iss.1 (2003)

Analysis of Impedance Spectroscopy Data Finding the Best System Function

S. Baltianski and Y. Tsur

Journal of Electroceramics, 10, 89-94, (2003)

2002

2001

Point Defect Concentrations in Barium Titanate Revisited

Y. Tsur and C.A. Randall

Journal of the American Ceramic Society, 84, 2147-49, (2001)

Site Occupancy of Rare Earth Cations in BaTiO3

Y. Tsur, A. Hitomi, I. Scrymgeour and C.A. Randall

Japanese Journal of Applied Physics, 40, Part 1, No.1, 255-258, (2001)

2000

Improving the Oxidation Resistance of base Metal Powders

Y. Tsur, J.H. Adair and C.A. Randall

Japanese Journal of Applied Physics, 39, Part 1, No.10, 6004-6007, (2000)

How Trivalent Amphoteric Dopants in BaTiO3 Ceramics Improve Reliability of Capacitors

Y. Tsur and C.A. Randall

“Fundamental Physics of Ferroelectrics”, Ed. R. Cohen, AIP New York, 283-287, (2000)

Analysis of X-Ray Powder Diffraction Data Using the Maximum Likelihood Estimation Method

Y. Tsur and C.A. Randall

Journal of the American Ceramic Society, 83, 2062-2066, (2000)

A Universal Analytical Approach to the Defect Chemistry of A+2B+4O3 Perovskites

Y. Tsur and C.A. Randall

“High Temperature Corrosion and Materials Chemistry”, Electrochemical Society, 502-513, (2000)

1999

Self-Compensation in Semiconductors

Y. Tsur and I. Riess

Physical Review B, 60, 8138-8146 (1999)

Doping of Ionic Compounds: Solubility Limit and Self-Compensation

Y. Tsur and I. Riess

Solid State Ionics, 119, 37-42, (1999)

Effect of Y- Doping on Dielectric Properties of BaTiO3 Films Deposited in Reducing Atmospheres Using Pulsed Laser Deposition

W.-Y. Choi, Y. Tsur, C.A. Randall and S. Trolier-McKinstry

MRS, Ferroelectric Thin Films VIII, 596, 487 (1999)

1998

Impurity Solubility Limits in Ionic Crystals, with Application to Cu2O

Invited: Y. Tsur and I. Riess

Zeitschrift fuer Physikalische Chemie, 207, 181-213, (1998)